Titanium boron nitride coatings were synthesized by ion beam assisted sputt
er deposition. Structural analysis showed that the coatings had a composite
structure comprising nanosized TiB2/TiN crystallites and a thin layer matr
ix of hexagonal BN. Although, the hardness of these Ti-B-N coatings was gen
erally lower than that of pure TiB2, improved anti-wear performance was obs
erved. This improvement is explained by the beneficial configuration of har
d nanoparticles embedded in a soft. lubricating matrix, which increases the
coating's capability to dissipate stress without brittle fracture. Effects
of process parameters, such as bombarding energy and nitrogen how rate wer
e also thoroughly studied. (C) 2001 Published by Elsevier Science B.V.