Coordination of a closo-cluster at rhodium and iridium

Authors
Marx, T Wesemann, L Dehnen, S
Citation
T. Marx et al., Coordination of a closo-cluster at rhodium and iridium, Z ANORG A C, 627(6), 2001, pp. 1146-1150
Citations number
48
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE
ISSN journal
00442313 → ACNP
Volume
627
Issue
6
Year of publication
2001
Pages
1146 - 1150
Database
ISI
SICI code
0044-2313(200106)627:6<1146:COACAR>2.0.ZU;2-1
Abstract
Stanna-closo-dodecaborate [Bu3MeN](2)[SnB11H11] reacts as a nucleophile wit h the rhodium and iridium electrophiles of type [Cp*M(bipy ' )Cl][BF4] unde r formation of a transition metal tin bond. The zwitterionic molecules [Cp* M(bipy ') (SnB11H11)] (with M = Rh, Lr) were characterized by NMR spectrosc opy, elemental analyses and X-ray crystal structure analyses. A high dipole moment of 25.67 D was calculated by DFT methods in the case of the rhodium derivative.