Gallium zigzag chains as an ordering principle in eta(5)-2,5-di-(t-butyl) phospholylgallium(I)

Authors
Chojnacki, J Baum, E Krossing, I Carmichael, D Mathey, F Schnockel, H
Citation
J. Chojnacki et al., Gallium zigzag chains as an ordering principle in eta(5)-2,5-di-(t-butyl) phospholylgallium(I), Z ANORG A C, 627(6), 2001, pp. 1209-1212
Citations number
23
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE
ISSN journal
00442313 → ACNP
Volume
627
Issue
6
Year of publication
2001
Pages
1209 - 1212
Database
ISI
SICI code
0044-2313(200106)627:6<1209:GZCAAO>2.0.ZU;2-M
Abstract
The solid state structure of eta (5)-2,5-di-(t-butyl)phospholylgallium(I) 1 was determined by X-ray diffraction at 190 K. The molecules of 1 are partl y organized in a for sandwich complexes new type of structure: a Ga zigzag chain in which the aromatic phospholyl rings alternate on both sides of the chain.