Rb5Mo27Se31, a novel ternary reduced molybdenum selenide containing Mo-12 and Mo-15 clusters

Authors
Picard, S Gougeon, P Potel, M
Citation
S. Picard et al., Rb5Mo27Se31, a novel ternary reduced molybdenum selenide containing Mo-12 and Mo-15 clusters, ACT CRYST C, 57, 2001, pp. 663-664
Citations number
20
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS
ISSN journal
01082701 → ACNP
Volume
57
Year of publication
2001
Part
6
Pages
663 - 664
Database
ISI
SICI code
0108-2701(200106)57:<663:RANTRM>2.0.ZU;2-0
Abstract
The crystal structure of Rb5Mo27Se31, pentarubidium heptacosamolybdenum hen triacontaselenium, consists of a mixture of Mo12Se14Se6 and Mo15Se17Se6 clu ster units in a 1:1 ratio. Both types of cluster are interconnected through inter-unit Mo-Se bonds. Rb+ cations occupy large voids between the differe nt cluster units.