Ferrocenecarboxylic acid-1,4-diazabicyclo[2.2.2]octane (2/1): sheets builtfrom O-H ... N and C-H ... O hydrogen bonds

Authors
Zakaria, CM Ferguson, G Lough, AJ Glidewell, C
Citation
Cm. Zakaria et al., Ferrocenecarboxylic acid-1,4-diazabicyclo[2.2.2]octane (2/1): sheets builtfrom O-H ... N and C-H ... O hydrogen bonds, ACT CRYST C, 57, 2001, pp. 687-689
Citations number
12
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS
ISSN journal
01082701 → ACNP
Volume
57
Year of publication
2001
Part
6
Pages
687 - 689
Database
ISI
SICI code
0108-2701(200106)57:<687:FA(SB>2.0.ZU;2-0
Abstract
In the title compound, 2[Fe(C5H5)(C6H5O2)].C6H12N2, the molecular component s are linked into finite three-component aggregates by strong O-H . . . N h ydrogen bonds [O . . . N 2.578 (4) and 2.604 (5) Angstrom; O-H . . . N 170 (5) and 174 (6)degrees]; these aggregates are further linked by C-H . . . O hydrogen bonds [C . . . O 3.327 (5)-3.401 (5) Angstrom; C-H . . . O 149-15 7 degrees] into continuous sheets in the form of (6,3) nets.