mu-Oxo-bis[(eta(5)-1,2-dicarbaundecaborato)bis(N,N-dimethylacetamidinato)tantalum] dichloromethane hemisolvate

Authors
Goeta, AE Hughes, AK Malget, JM
Citation
Ae. Goeta et al., mu-Oxo-bis[(eta(5)-1,2-dicarbaundecaborato)bis(N,N-dimethylacetamidinato)tantalum] dichloromethane hemisolvate, ACT CRYST C, 57, 2001, pp. 702-703
Citations number
15
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS
ISSN journal
01082701 → ACNP
Volume
57
Year of publication
2001
Part
6
Pages
702 - 703
Database
ISI
SICI code
0108-2701(200106)57:<702:M>2.0.ZU;2-U
Abstract
The structure of the title compound, [Ta2O(C2B9H11)(2)(C4H9N2)(4)].0.5CH(2) Cl(2), contains two (C2B9H11)Ta[NC(Me)NMe2](2) units bridged by a nearly li near [Ta-O-Ta 163.4 (4)degrees] mu -oxo ligand. The dichloromethane molecul e lies on a twofold axis.