The use of electron paramagnetic resonance (EPR) spectroscopy to study the
chemistry of oxide surfaces and catalysis is discussed. Emphasis is placed
on those aspects of tire techniques that are directly related to the specif
icity of heterogeneous systems, investigations of surfaces and catalytic re
actions. The characteristic features of EPR spectra of high-surface oxide m
aterials are analyzed, and the typical means employed to increase the amoun
t of extractable information are presented. A brief survey of new potential
ities of continuous-wave EPR and typical applications is also provided.