Equilibrium between neutral hexacoordinate silicon complexes and ionic pentacoordinate siliconium salts through fast dissociation-recombination of the Si-Cl bond

Authors
Kingston, V Gostevskii, B Kalikhman, I Kost, D
Citation
V. Kingston et al., Equilibrium between neutral hexacoordinate silicon complexes and ionic pentacoordinate siliconium salts through fast dissociation-recombination of the Si-Cl bond, CHEM COMMUN, (14), 2001, pp. 1272-1273
Citations number
14
Categorie Soggetti
Chemistry
Journal title
CHEMICAL COMMUNICATIONS
ISSN journal
13597345 → ACNP
Issue
14
Year of publication
2001
Pages
1272 - 1273
Database
ISI
SICI code
1359-7345(2001):14<1272:EBNHSC>2.0.ZU;2-8
Abstract
Equilibrium between neutral hexacoordinate silicon complexes and ionic sili conium chlorides, which is highly temperature, solvent, counterion, ligand and substituent dependent, was observed by low temperature Si-29 NMR and co nfirmed by crystal analysis.