The X-ray crystal structure of N,S-bis[(4 '-chloro-2,2 ': 6 ',2 '' terpyridine)platinum(II)]-2-mercaptoimidazole tris-hexafluorophosphate and tris[( 2,2 ': 6 ',2 ''-terpyridine)platinum(II)]sulfonium tetra-perchlorate

Authors
Lowe, G Ross, SA Probert, M Cowley, A
Citation
G. Lowe et al., The X-ray crystal structure of N,S-bis[(4 '-chloro-2,2 ': 6 ',2 '' terpyridine)platinum(II)]-2-mercaptoimidazole tris-hexafluorophosphate and tris[( 2,2 ': 6 ',2 ''-terpyridine)platinum(II)]sulfonium tetra-perchlorate, CHEM COMMUN, (14), 2001, pp. 1288-1289
Citations number
9
Categorie Soggetti
Chemistry
Journal title
CHEMICAL COMMUNICATIONS
ISSN journal
13597345 → ACNP
Issue
14
Year of publication
2001
Pages
1288 - 1289
Database
ISI
SICI code
1359-7345(2001):14<1288:TXCSON>2.0.ZU;2-F
Abstract
Intramolecular stacking of the (4-chloro-2,2':6',2"-terpyridine)platinum(II ) moieties occurs in N,S-bis[(4'-chloro-2,2':6,2-terpyridine) platinum(II)] -2-mercaptoimidazole tris-hexafluorophosphate; N,S-bis[(2,2':6',2"-terpyrid ine)-platinum(II)]thioacetimine trinitrate is slowly transformed in aqueous solution to the molecular propeller-like tris[(2,2':6',2"-terpyridine)plat inum(II)] sulfonium ion.