Chemical composition of structures obtained inside quartz crystals by sodium electrodiffusion

Citation
B. Iliescu et al., Chemical composition of structures obtained inside quartz crystals by sodium electrodiffusion, CRYST RES T, 36(4-5), 2001, pp. 403-410
Citations number
8
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
CRYSTAL RESEARCH AND TECHNOLOGY
ISSN journal
02321300 → ACNP
Volume
36
Issue
4-5
Year of publication
2001
Pages
403 - 410
Database
ISI
SICI code
0232-1300(2001)36:4-5<403:CCOSOI>2.0.ZU;2-#
Abstract
Dendritic structures were grown inside quartz crystals by electrodiffusion of sodium ions from a NaCl layer at the anode. An experimental arrangement using a point cathode and a graphite plate anode was employed. X-ray diffra ction experiments were carried out, the structures chemical composition was found to be a mixture of sodium silicates. The chemical composition evolut ion in time was observed. There were made VIS and UV optical absorption spe ctroscopy measurements of these structures, a colloidal band being found. T hermoluminescence glow curves were measured. Based on the experimental resu lts and observations a growth model is proposed.