In the United States, the newly promulgated disinfectant/disinfection by-pr
oduct (D/DBP) regulations force water treatment utilities to be more concer
ned with finished and distributed water qualities. In this study, monitorin
g of DBP formation was conducted from three French water treatment plants t
rying to assess DBP variations through time and space. Compared to the in-p
lant total trihalomethanes (TTHM) levels, TTHM levels in the distribution s
ystem increased from less than 150% to more than 300%. Significant variatio
ns for TTHM and bromate (BrO3-) levels throughout the seasons were also obs
erved; generally higher levels in the summer and lower levels in the winter
. Combining chemical DBP models (empirical power functional models) and hyd
raulic simulations, DBPs including TTHM and BrO3- were successfully simulat
ed from the full-scale monitoring data, indicating that empirical DBP model
can be a potential tool to access DBP formation in actual plants. This stu
dy also provides the protocols to assess DBP simulations in the water treat
ment systems.