Mechanical and order rigidity of nematic elastomers

Citation
Gg. Pereira et M. Warner, Mechanical and order rigidity of nematic elastomers, EUR PHY J E, 5(3), 2001, pp. 295-307
Citations number
14
Categorie Soggetti
Apllied Physucs/Condensed Matter/Materiales Science
Journal title
EUROPEAN PHYSICAL JOURNAL E
ISSN journal
12928941 → ACNP
Volume
5
Issue
3
Year of publication
2001
Pages
295 - 307
Database
ISI
SICI code
1292-8941(200106)5:3<295:MAORON>2.0.ZU;2-J
Abstract
We calculate the ratio of moduli for extension parallel and perpendicular t o tile director of nematic elastomers. Elastomers in practice are not ideal nematics with a jump from a finite to zero-order parameter with increasing temperature. Some classes behave as if under effective external fields. Th ese are really internal in origin and leave the system subcritical (still w ith jumps) or supercritical. We give expressions for general non-ideality, and memory of formation conditions; along with its translation into values of the "fields''. For the case of supercritical fields, we find that tile m odulus ratio deviates more from unity, in accord with experiment, than in t he subcritical case.