GdBi5Fe2Ti3O18 (GBFT), a compound of Aurivillius family, was prepared by so
lid state reaction method. Complex impedance measurement was made on these
samples from room temperature to 500 degrees C in the frequency range of 1
kHz(-1) MHz. Cole-Cole plots were found to become very broad near 400 degre
esC. Dielectric and de conductivity measurements were made on these samples
. The results are analysed to understand the conductivity mechanism.