Syntheses and thermal properties of poly(hydroxy)urethanes by polyadditionreaction of bis(cyclic carbonate) and diamines

Authors
Kim, MR Kim, HS Ha, CS Park, DW Lee, JK
Citation
Mr. Kim et al., Syntheses and thermal properties of poly(hydroxy)urethanes by polyadditionreaction of bis(cyclic carbonate) and diamines, J APPL POLY, 81(11), 2001, pp. 2735-2743
Citations number
13
Categorie Soggetti
Organic Chemistry/Polymer Science","Material Science & Engineering
Journal title
JOURNAL OF APPLIED POLYMER SCIENCE
ISSN journal
00218995 → ACNP
Volume
81
Issue
11
Year of publication
2001
Pages
2735 - 2743
Database
ISI
SICI code
0021-8995(20010912)81:11<2735:SATPOP>2.0.ZU;2-7
Abstract
In this study, we synthesized poly(hydroxy)urethanes by the polyaddition re action of bis(cyclic carbonate) and diamine. Bis(cyclic carbonate) was prep ared from diglycidyl ether based on bisphenol S and carbon dioxide. Thermal properties and solubilities of the poly(hydroxy)urethanes of five differen t diamines were compared. The thermal properties of the poly(hydroxy)uretha nes depended on the structure of the diamine as well as the structure of th e monomer. These poly(hydroxy)urethanes were soluble only in aprotic solven ts because of the hydrophilic character of the hydroxy group. (C) 2001 John Wiley & Sons, Inc.