CONFIRMATION OF THE STEREOCHEMISTRY OF 7-BETA-ANGELYL-1-METHYLENE-8-ALPHA-PYRROLIZIDINE

Authors
LOGIE CG LIDDELL JR KAYE PT
Citation
Cg. Logie et al., CONFIRMATION OF THE STEREOCHEMISTRY OF 7-BETA-ANGELYL-1-METHYLENE-8-ALPHA-PYRROLIZIDINE, South African Journal of Chemistry, 50(2), 1997, pp. 72-74
Citations number
14
Categorie Soggetti
Chemistry
Journal title
South African Journal of Chemistry → ACNP
ISSN journal
03794350
Volume
50
Issue
2
Year of publication
1997
Pages
72 - 74
Database
ISI
SICI code
0379-4350(1997)50:2<72:COTSO7>2.0.ZU;2-N
Abstract
The (7R,8R) stereochemistry of naturally occurring 7 beta-angelyl-1-me thylene-8 alpha-pyrrolizidine 5 was confirmed by subjecting a mixture of a synthetic standard and the natural product to various chiral diff erentiating techniques. The synthetic 7 beta-angelyl-1-methylene-8 alp ha-pyrrolizidine 1 was prepared from enantiomerically pure retronecine 3.