Hazards caused by leakage of hydrocarbons have long been a problem. In this
paper, the critical initiation energy and explosion limits of some hydroca
rbon-air mixtures have been measured in confined (rectangle shock tube) and
unconfined (plastic bag) condition tests. Two dimensionless parameters are
suggested to compare the fire and explosion hazards of different hydrocarb
ons. Additionally, a series of experiments was performed to determine the i
nfluence of chemical additives on the fire and explosion hazards of some hy
drocarbon-air mixtures in confined (rectangle shock tube) tests. These resu
lts relate directly to flammability and reactivity of hydrocarbon air mixtu
res. Such measurements are very important for hydrocarbon safety. (C) 2001
Elsevier Science B.V. All rights reserved.