CRYSTAL-STRUCTURE AND PARAMAGNETIC BEHAVIOR OF EPSILON-WO3-X

Citation
Ekh. Salje et al., CRYSTAL-STRUCTURE AND PARAMAGNETIC BEHAVIOR OF EPSILON-WO3-X, Journal of physics. Condensed matter, 9(31), 1997, pp. 6563-6577
Citations number
33
Categorie Soggetti
Physics, Condensed Matter
ISSN journal
09538984
Volume
9
Issue
31
Year of publication
1997
Pages
6563 - 6577
Database
ISI
SICI code
0953-8984(1997)9:31<6563:CAPBOE>2.0.ZU;2-8
Abstract
The crystal structure of the lowest-temperature E-phase of WO3 has bee n determined as a function of temperature by neutron powder diffractio n. The diffraction measurements show that there are no additional phas es at low temperatures. Magnetic measurements suggest that no supercon ductivity exists at temperatures as low as 9 x 10(-5) K, but instead, an increase of the magnetic susceptibility according to a paramagnetic Curie law was found. This observation indicates that unpaired carrier s persist in the sample, after cooling to very low temperatures.