The reduction of metal salts dissolved in the aqueous domains of the lyotro
pic liquid crystalline phases of surfactants provides a versatile route to
a range of mesoporous metals with aligned pore systems having a high degree
of spatial periodicity. Here we report that the co-reduction of binary mix
tures of metal compounds dissolved in the hexagonal phase of a non-ionic su
rfactant leads to bimetallic alloy powders that have a long-ranged porous n
anostructure and high specific surface areas. These results indicate that t
he use of liquid crystalline reaction mixtures could provide a new route to
alloys of importance for applications in catalysis. (C) 2001 Published by
Elsevier Science B.V.