Electron injection into porous TiO2 is investigated by current-voltage, dar
k current transients, impedance spectroscopy and photocurrent transients. S
trong electron injection takes place and the existence of positive compensa
ting charge has been shown. The compensating charge is originated by polari
zation of the TiO2 nanoparticles. A scenario has been proposed for the proc
esses of injection and formation of conducting channels in porous TiO2.