Studies on stereocontrolled epoxidations of bis-alicyclic alcohols in steroidal skeletons: preparation of eight diastereomerically pure epoxides fromcholest-4-en-3 beta,6 beta-; -3 beta,6 alpha-; -3 alpha,6 beta- and -3 alpha,6 alpha-diols

Authors
Zhao, KJ Wang, YF Billington, DC
Citation
Kj. Zhao et al., Studies on stereocontrolled epoxidations of bis-alicyclic alcohols in steroidal skeletons: preparation of eight diastereomerically pure epoxides fromcholest-4-en-3 beta,6 beta-; -3 beta,6 alpha-; -3 alpha,6 beta- and -3 alpha,6 alpha-diols, TETRAHEDR-A, 12(8), 2001, pp. 1211-1217
Citations number
25
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
TETRAHEDRON-ASYMMETRY
ISSN journal
09574166 → ACNP
Volume
12
Issue
8
Year of publication
2001
Pages
1211 - 1217
Database
ISI
SICI code
0957-4166(20010521)12:8<1211:SOSEOB>2.0.ZU;2-B
Abstract
Eight diastereomerically pure epoxides have been prepared from cholest-4-en -3 beta .6 beta: -3 beta .6 alpha-: -3 alpha .6 beta- and -3 alpha .6 alpha -diols via a combination of steric, protecting group and oxidant effects o n stereocontrolled epoxidations of a bis-alicyclic alcohol system within th e steroidal skeleton. (C) 2001 Elsevier Science Ltd. All rights reserved.