Elastic and thermoelastic properties of the 21 title crystalline species ha
ve been determined from ultrasonic resonant frequencies of plates and their
shift upon variation of temperature, respectively. In addition, the tensor
s of thermal expansion have been measured by the aid of a Fizeau interferom
eter.
An analysis of the elastic behaviour of organic crystals, including earlier
elastic data of other organic compounds taken from the literature, reveale
d common features of organic crystals and organic liquids in respect to the
scalar invariants C=(c(11) + c(22) + c(33) + c(44) + c(55) + c(66) + c(12)
+ c(13) + c(23))/9 and d log C/dT, T temperature. especially in the case o
f Van-der-Waals crystals. Contrary to ionic crystals the invariant C increa
ses in these crystals with larger molecular volume. Crystals with strong hy
drogen bonds like dicarboxylic or sulfonic acids behave rather like ionic c
rystals. The influence of a small molecular elastic stiffness, as observed
in plastic crystals, is clearly recognizable in the elastic properties. The
impact of structural details on the invariant C and its logarithmic temper
ature derivative is surprisingly small.