Dichloro(D-methionine-N,S)-platinum(II) at 130 K

Authors
Llorca, J Molins, E Espinosa, E Mata, I Miravitlles, C Cervantes, G Caubet, A Moreno, V
Citation
J. Llorca et al., Dichloro(D-methionine-N,S)-platinum(II) at 130 K, ACT CRYST C, 57, 2001, pp. 804-806
Citations number
16
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS
ISSN journal
01082701 → ACNP
Volume
57
Year of publication
2001
Part
7
Pages
804 - 806
Database
ISI
SICI code
0108-2701(200107)57:<804:DA1K>2.0.ZU;2-M
Abstract
The asymmetric unit of the title compound, [PtCl2-(C5H11NO2S)], a D-methion ine derivative, contains two molecules with opposite chirality at the S ato ms. The amino acid acts as a bidentate ligand and coordinates simultaneousl y through the N (amino) and S (thioether) atoms. The molecules are packed i n pairs which are connected through two hydrogen bonds between the protonat ed carboxyl groups, with O . . .O distances of 2.633 (10) and 2.663 (12) An gstrom.