10-(4-Fluorophenyl)-3,3,6,6,9-penta-methyl-3,4,6,7,9,10-hexahydro-acridine-1,8(2H,5H)-dione and 10-(4-fluorophenyl)-3,3,6,6-tetra-methyl-9-propyl-3,4,6,7,9,10-hexa-hydroacridine-1,8(2H,5H)-dione
As. Pandi et al., 10-(4-Fluorophenyl)-3,3,6,6,9-penta-methyl-3,4,6,7,9,10-hexahydro-acridine-1,8(2H,5H)-dione and 10-(4-fluorophenyl)-3,3,6,6-tetra-methyl-9-propyl-3,4,6,7,9,10-hexa-hydroacridine-1,8(2H,5H)-dione, ACT CRYST C, 57, 2001, pp. 821-824
10-(4-Fluorophenyl)-3,3,6,6,9-pentamethyl-3,4,6,7,9,10-hexa- hydroacridine-
1,8(2H,5H)-dione, C24H28FNO2, (I), crystallizes with two crystallographical
ly independent molecules (which differ slightly in conformation), while 10-
(4-fluorophenyl)-9-propyl-3,3,6,6-tetramethyl-3,4,6,7,9,10-hexahydro- acrid
ine-1,8(2H,5H)-dione, C26H32FNO2, (II), crystallizes with one molecule per
asymmetric unit. In both structures, the central ring in the acridine moiet
y is in a sofa conformation, while the outer rings adopt intermediate half-
chair/sofa conformations. The central pyridine ring is orthogonal to the su
bstituted phenyl ring. In both structures, the packing of the crystal is st
abilized by C-H . . .O intermolecular hydrogen bonds.