5-(2-pyridyl)-1,3-dithiane-2-thione

Citation
A. Hazell et al., 5-(2-pyridyl)-1,3-dithiane-2-thione, ACT CRYST C, 57, 2001, pp. 859-860
Citations number
9
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS
ISSN journal
01082701 → ACNP
Volume
57
Year of publication
2001
Part
7
Pages
859 - 860
Database
ISI
SICI code
0108-2701(200107)57:<859:5>2.0.ZU;2-C
Abstract
The title compound, C9H9NS3, crystallizes with two molecules in the asymmet ric unit. In both molecules, the dithiane-2-thione rings adopt a symmetric half-boat conformation with the C atom opposite the C-S-thione bond out of the plane. The pyridine ring is in an equatorial position and is twisted ou t of the plane of the half-boat by 82.7 (2) and 84.5 (2)degrees in the two molecules, so that the N atom is trans to the axial C-H bond in both cases.