Langmuir probe is an important diagnostic tool for measuring plasma paramet
ers. A tuned single probe has been used to diagnostic the electron energy d
istribution function in Ar radio frequency (13.56MHz) glow plasma. The seco
nd derivative of probe I-V characteristic was obtained after using numerica
l filter procedure to eliminate the statistical noise in measured I-V chara
cteristic. A differential circuit has been designed and applied to measure
the second derivative of I-V characteristic on line under the same discharg
e conditions. The results of the two methods are in agreement with each oth
er.