My. Liao et al., Influence of ion energy and deposition temperature on the surface morphology of carbon films deposited by ion beams, ACT PHY C E, 50(7), 2001, pp. 1324-1328
Carbon films were deposited by mass-selected ion beam technique with ion en
ergies 50-200eV at a substrate temperature from room temperature to 80 degr
eesC,. For the energies used, smooth diamond-like carbon films were deposit
ed at room temperature. When the substrate temperature was 600 degreesC,rou
gh graphitic films were produced. But highly oriented carbon tubes were obs
erved when the energies were larger than 140eV at 800 degreesC. They were p
erpendicular to the surface and parallel to each other. preferred orientati
on of graphite basic plane was observed by high-resolution electron microsc
opy. Shallow ion implantation and stress are responsible for this orientati
on.