Analysis of solid samples by capillary electrophoresis using a gas extraction sampling device in a flow system

Citation
Ag. Lista et al., Analysis of solid samples by capillary electrophoresis using a gas extraction sampling device in a flow system, ANALYT CHIM, 438(1-2), 2001, pp. 315-322
Citations number
24
Categorie Soggetti
Spectroscopy /Instrumentation/Analytical Sciences
Journal title
ANALYTICA CHIMICA ACTA
ISSN journal
00032670 → ACNP
Volume
438
Issue
1-2
Year of publication
2001
Pages
315 - 322
Database
ISI
SICI code
0003-2670(20010703)438:1-2<315:AOSSBC>2.0.ZU;2-6
Abstract
A gas extraction sampling device integrated in a continuous Row system (CFS ) was coupled to a capillary electrophoresis equipment (CE) for the direct determination of trimethylamine (TMA) and related amines in fish sample. Th is arrangement allowed the direct introduction and treatment of these solid samples with a high level of automation. The amine compounds were extracte d from fish samples in the sampling unit, then they were conditioned in the CFS and injected into the CE vials via a programmable arm. Methylamine, di methylamine, trimethylamine, ethylamine, propylamine, diethylamine and trie thylamine were separated and quantified. The concentration of trimethylamin e (the major amine in fish) in the analysed real sample was ranged from 20 to 250 mg g(-1). (C) 2001 Elsevier Science B.V. All rights reserved.