N2O and NO nitridation by either annealing or direct growth of gate oxides
on 4H SiC is analyzed in this letter. The analysis is based on x-ray photoe
lectron spectroscopy binding energies and secondary ion mass spectroscopy d
epth profiles of nitrogen at the SiO2-SiC interface. A clean SiO2-SiC inter
face is found in both NO and N2O annealed/grown samples, as opposed to the
interface annealed in Ar which exhibits complex suboxides and oxide-carbon
compounds. The results demonstrate that nitridation in the industry-preferr
ed N2O ambient could be as effective as nitridation in NO, provided appropr
iate process optimization is performed. (C) 2001 American Institute of Phys
ics.