Do we need pseudocomponents?

Authors
Citation
E. Eckert, Do we need pseudocomponents?, CHEM LISTY, 95(6), 2001, pp. 368-373
Citations number
11
Categorie Soggetti
Chemistry
Journal title
CHEMICKE LISTY
ISSN journal
00092770 → ACNP
Volume
95
Issue
6
Year of publication
2001
Pages
368 - 373
Database
ISI
SICI code
0009-2770(2001)95:6<368:DWNP>2.0.ZU;2-L
Abstract
A comparison of computation results for molecular weight, critical temperat ure, critical pressure and the acentric factor for 98 pure components using different methods frequently utilised for pseudocomponents characterising crude oil and petroleum fractions was made. It is shown that these methods mostly afford the estimated parameters with large errors. On the example of the true boiling point characterisation test, the possibility to use real components instead of pseudocomponents is shown. For real components, all t hermodynamic characteristics are known with high accuracy. In addition, by the choice of real components, the user can take into account some specific ities in the composition of the studied mixture.