In an initially homogeneous alloy quenched from high temperature, local ord
ering and/or phase Separation may occur on the way towards thermodynamic eq
uilibrium at a lower temperature. Some of the related diffuse scattering ef
fects, including those around the primary beam (small-angle scattering), ar
e presented, and some recent results of X-ray and neutron scattering studie
s of short-range order and decomposition in some alloys are discussed.