D. Bauman et al., Determination of the order parameter of 4-(trans-4 '-n-hepty-cyclohexyl)-isothiocyanato-benzene by means of dielectric relaxation spectroscopy, IEEE DIELEC, 8(3), 2001, pp. 381-384
Citations number
14
Categorie Soggetti
Eletrical & Eletronics Engineeing
Journal title
IEEE TRANSACTIONS ON DIELECTRICS AND ELECTRICAL INSULATION
Studies of the dielectric relaxation were made for the isotropic and nemati
c phases of 4-trans-4 ' -n-(heptylcyclohexyl)isothiocyanatobenzene, (C7H15-
CyHx-Ph-N=C=S) (7CHBT) in the frequency range from 100 kHz to 1 GHz. In the
nematic phase two relaxation processes were recorded for the dielectric pe
rmittivity component measured parallel to the molecular orientation (direct
or (n) over right arrow) and three relaxation processes for the perpendicul
ar permittivity component. The elementary contributions to the total dielec
tric absorption are found to be of the Debye-type. The strength of the nema
tic potential and the nematic order parameter as a function of temperature
were estimated. The results obtained were compared with the predictions of
the Maier-Saupe theory.