Synthesis, structure and conduction of a novel radical cation salt, (ET)(5)DY(NCS)(6)NO3.C2H5OH

Authors
Kushch, ND Kazheva, ON Gritsenko, VV Buravov, LI Dyachenko, OA Van, KV
Citation
Nd. Kushch et al., Synthesis, structure and conduction of a novel radical cation salt, (ET)(5)DY(NCS)(6)NO3.C2H5OH, IEEE DIELEC, 8(3), 2001, pp. 429-431
Citations number
6
Categorie Soggetti
Eletrical & Eletronics Engineeing
Journal title
IEEE TRANSACTIONS ON DIELECTRICS AND ELECTRICAL INSULATION
ISSN journal
10709878 → ACNP
Volume
8
Issue
3
Year of publication
2001
Pages
429 - 431
Database
ISI
SICI code
1070-9878(200106)8:3<429:SSACOA>2.0.ZU;2-K
Abstract
A new radical cation salt (ET)(5)[Dy(NCS)(6)NO3]. (C2H5OH based on a comple x dysprosium anion was prepared by electrochemical oxidation of Bis (ethyle nedithio)tetrathiafulvalene (ET) in a chlorobenzene-ethanol solution. Its c rystal structure and conducting properties were studied. The salt has a lay ered crystal structure with a new type of packing of the radical cation lay er, which is called omega type. Its electrical properties show that this sa lt is a semiconductor.