Nd. Kushch et al., Synthesis, structure and conduction of a novel radical cation salt, (ET)(5)DY(NCS)(6)NO3.C2H5OH, IEEE DIELEC, 8(3), 2001, pp. 429-431
Citations number
6
Categorie Soggetti
Eletrical & Eletronics Engineeing
Journal title
IEEE TRANSACTIONS ON DIELECTRICS AND ELECTRICAL INSULATION
A new radical cation salt (ET)(5)[Dy(NCS)(6)NO3]. (C2H5OH based on a comple
x dysprosium anion was prepared by electrochemical oxidation of Bis (ethyle
nedithio)tetrathiafulvalene (ET) in a chlorobenzene-ethanol solution. Its c
rystal structure and conducting properties were studied. The salt has a lay
ered crystal structure with a new type of packing of the radical cation lay
er, which is called omega type. Its electrical properties show that this sa
lt is a semiconductor.