IMPROVED PREPARATION OF N-TRIMETHYLSILYLPYRIDINIUM TRIFLATE, N-TRIPHENYLSILYLPYRIDINIUM TRIFLATE, N-TRIISOPROPYLSILYLPYRIDINIUM TRIFLATE AND THEIR USE IN SILYLATING ALCOHOLS TO SILYL ETHERS

Authors
OLAH GA KLUMPP DA
Citation
Ga. Olah et Da. Klumpp, IMPROVED PREPARATION OF N-TRIMETHYLSILYLPYRIDINIUM TRIFLATE, N-TRIPHENYLSILYLPYRIDINIUM TRIFLATE, N-TRIISOPROPYLSILYLPYRIDINIUM TRIFLATE AND THEIR USE IN SILYLATING ALCOHOLS TO SILYL ETHERS, Synthesis, (7), 1997, pp. 744
Citations number
10
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Synthesis → ACNP
ISSN journal
00397881
Issue
7
Year of publication
1997
Database
ISI
SICI code
0039-7881(1997):7<744:IPONTN>2.0.ZU;2-G
Abstract
N-Silylpyridinium triflates 1a-c have been prepared in excellent yield from the corresponding allyl silanes by reaction with triflic acid fo llowed by pyridine. Compounds 1 a-c were used to prepare silyl ethers from alcohols in generally high yield. A convenient procedure has been developed which enables the silylation of alcohols without an aqueous workup in the product isolation.