A theory for the magnetic hyperfine interactions in the microwave spectrumof NO-HF

Authors
Dennis, CR Whitham, CJ Howard, BJ
Citation
Cr. Dennis et al., A theory for the magnetic hyperfine interactions in the microwave spectrumof NO-HF, J CHEM PHYS, 115(3), 2001, pp. 1355-1366
Citations number
25
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
JOURNAL OF CHEMICAL PHYSICS
ISSN journal
00219606 → ACNP
Volume
115
Issue
3
Year of publication
2001
Pages
1355 - 1366
Database
ISI
SICI code
0021-9606(20010715)115:3<1355:ATFTMH>2.0.ZU;2-J
Abstract
A theory is presented for the fine and hyperfine interactions in the (2)Pi state open shell complexes like NO-HF containing remote magnetic nuclei. Th e nitrogen hyperfine Hamiltonian is based on the conventional Frosch and Fo ley treatment for diatomic radicals. An alternative treatment has been deve loped for the intermolecular hydrogen and fluorine magnetic hyperfine inter actions based on a dipolar model for both electron spin and orbital magneti c moments. (C) 2001 American Institute of Physics.