Propagation and interaction of cellular fronts in a closed system

Citation
M. Fuentes et al., Propagation and interaction of cellular fronts in a closed system, J PHYS CH A, 105(27), 2001, pp. 6769-6774
Citations number
22
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
JOURNAL OF PHYSICAL CHEMISTRY A
ISSN journal
10895639 → ACNP
Volume
105
Issue
27
Year of publication
2001
Pages
6769 - 6774
Database
ISI
SICI code
1089-5639(20010712)105:27<6769:PAIOCF>2.0.ZU;2-7
Abstract
We experimentally study the development of cellular acidity fronts during t he chlorite oxidation of tetrationate performed in a thin layer of viscous solution containing different amounts of polyelectrolyte. These properties and the interaction between fronts are investigated as a function of initia l chemical concentrations. The observations are compared to numerical resul ts obtained with a skeleton kinetic model of the reaction using a two-dimen sional finite element integration scheme. The agreements with observations are striking.