Citation
C. Gejke et al., The effect of lithium insertion on the structure of tin oxide-based glasses, J POWER SOU, 97-8, 2001, pp. 226-228
Citations number
8
Categorie Soggetti
Physical Chemistry/Chemical Physics","Environmental Engineering & Energy
Journal title
JOURNAL OF POWER SOURCES
ISSN journal
03787753
→ ACNP
Volume
97-8
Year of publication
2001
Pages
226 - 228
Database
ISI
SICI code
0378-7753(200107)97-8:<226:TEOLIO>2.0.ZU;2-W
Abstract
Two different SnO-based glasses, Sn2B3O6.5 and Sn2B2AlO6.5, have been exami
ned with FT-IR and Raman spectroscopy at different stages during the first
electrochemical cycle, It was found that some disruption of the connection
between berate units in the network occurred during cycling. There was also
an irreversible formation of Li3BO3 that can be related to the large capac
ity loss. (C) 2001 Elsevier Science B.V. All rights reserved.