Thermodynamic properties of aqueous potassium fluoride under superambient conditions

Authors
Citation
B. Das et Ks. Pitzer, Thermodynamic properties of aqueous potassium fluoride under superambient conditions, J SOL CHEM, 30(5), 2001, pp. 489-496
Citations number
14
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
JOURNAL OF SOLUTION CHEMISTRY
ISSN journal
00959782 → ACNP
Volume
30
Issue
5
Year of publication
2001
Pages
489 - 496
Database
ISI
SICI code
0095-9782(200105)30:5<489:TPOAPF>2.0.ZU;2-F
Abstract
Using the ion-interaction or virial coefficient approach developed by Fitte r, the pressure dependences of the osmotic and activity coefficients for KF (aq.) up to 473.15 K and 2.5.0 mol-kg(-1) have been calculated from litera ture data for the apparent molar volumes of KF (aq.). These pressure depend encies were combined with the osmotic and activity coefficient at 0.1 MPa o r p(sat), obtained from the model of Saluja et al. to yield a comprehensive set of thermodynamic properties for KF (aq.) at temperatures from 298.15 t hrough 473.15 K, pressures 10, 20, and 30 MPa, and molalities to 2.5 mol-kg (-1).