Thermal decomposition of Bi(III), Cd(II), Pb(II) and Cu(II) thiocyanates

Authors
Ptaszynski, B Skiba, E Krystek, J
Citation
B. Ptaszynski et al., Thermal decomposition of Bi(III), Cd(II), Pb(II) and Cu(II) thiocyanates, J THERM ANA, 65(1), 2001, pp. 231-239
Citations number
15
Categorie Soggetti
Spectroscopy /Instrumentation/Analytical Sciences
Journal title
JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY
ISSN journal
13886150 → ACNP
Volume
65
Issue
1
Year of publication
2001
Pages
231 - 239
Database
ISI
SICI code
1388-6150(2001)65:1<231:TDOBCP>2.0.ZU;2-V
Abstract
Thermal decomposition of Bi(SCN)(3), Cd(SCN)(2), Pb(SCN)(2) and Cu(SCN)(2) has been studied. The thermal analysis curves and the diffraction patterns of the solid intermediate and final products of the pyrolysis are presented . The gaseous products of the decomposition (SO2 and CO2) were detected and quantitatively determined. Thermal, X-ray and chemical analyses have been used to establish the nature of the reactions occurring at each stage in th e decomposition.