Vv. Molchanov et Ra. Buyanov, Scientific grounds for the application of mechanochemistry to catalyst preparation, KINET CATAL, 42(3), 2001, pp. 366-374
It is shown that mechanochemical activation is efficient in creating waste-
free energy-saving methods for the preparation of hydride catalysts, hetero
poly acid catalysts, and catalysts for hydrocarbon decomposition into hydro
gen and carbon materials, as well for the syntheses of earlier unknown cata
lytic systems. The capabilities of the mechanochemical methods are demonstr
ated on modifying the catalytic properties of catalysts and supports: an in
crease in the strength and catalytic activity, sorption properties, etc. Ad
hesion theory applied to melts helps to describe the mechanism of mechanoch
emical synthesis of catalytic systems.