Epitaxial layers of GaAs, when thick enough, are now recognized as good can
didates for X-ray imaging. In order to overcome the limitation in the size
of the substrates for large imaging applications, we are developing a growt
h technique by chemical reaction which allows to obtain several hundred mic
rons thick polycrystalline layers, i.e. of unlimited dimensions, in few hou
rs. The size and orientation of the grains can be controlled to some extent
through the growth conditions. We shall present data concerning optical (I
R absorption, luminescence), structural (double X-ray diffraction) and elec
trical (resistivity, current-voltage characteristics of Schottky barriers)
characterizations performed on 300 mum thick non-intentionally doped layers
in which the crystallites, of columnar structure, are [1 1 I] oriented and
of diameter 70 +/- IO mum. We now aim at controlling the location of the c
rystallites on the glass substrate in order to get a regular pattern and at
resuming a new epitaxy on a polycrystalline surface. (C) 2001 Elsevier Sci
ence B.V. All rights reserved.