Matrix-assisted pulsed laser evaporation of polymeric materials: a molecular dynamics study

Citation
Te. Itina et al., Matrix-assisted pulsed laser evaporation of polymeric materials: a molecular dynamics study, NUCL INST B, 180, 2001, pp. 238-244
Citations number
15
Categorie Soggetti
Spectroscopy /Instrumentation/Analytical Sciences","Instrumentation & Measurement
Journal title
NUCLEAR INSTRUMENTS & METHODS IN PHYSICS RESEARCH SECTION B-BEAM INTERACTIONS WITH MATERIALS AND ATOMS
ISSN journal
0168583X → ACNP
Volume
180
Year of publication
2001
Pages
238 - 244
Database
ISI
SICI code
0168-583X(200106)180:<238:MPLEOP>2.0.ZU;2-N
Abstract
Matrix-assisted pulsed laser evaporation (MAPLE) has been recently develope d to deposit high-quality thin films for a wide range of polymeric material s. To analyze the evaporation of polymer molecules in MAPLE, we present a m olecular dynamics (MD) simulation of laser ablation where the target materi al is modeled as a solution of polymer molecules in a molecular matrix. The breathing sphere model is used for MD simulations of laser ablation of the molecular matrix. Polymer molecules are described using a bead-spring mode l, where each bead represents one or several polymer groups. The initial st age of polymer ejection is investigated at different laser fluences and pul se durations. The influence of polymer molecules on the stability of cluste rs formed in the plume and the processes that can lead to polymer decomposi tion are discussed. (C) 2001 Elsevier Science B.V. All rights reserved.