Thiadiazole-derived expanded heteroazaporphyrinoids

Citation
Mk. Islyaikin et al., Thiadiazole-derived expanded heteroazaporphyrinoids, ORG LETT, 3(14), 2001, pp. 2153-2156
Citations number
38
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
ORGANIC LETTERS
ISSN journal
15237060 → ACNP
Volume
3
Issue
14
Year of publication
2001
Pages
2153 - 2156
Database
ISI
SICI code
1523-7060(20010712)3:14<2153:TEH>2.0.ZU;2-Y
Abstract
[GRAPHICS] Heteroannulenes 1 and 3 containing three subunits of isoindole or pyrrole, respectively, three 1,3,4-thiadiazole moieties, and six aza-bridges have be en synthesized by reaction of the corresponding diiminoisoindoline or diimi nopyrroline with 2,5-diamino-1,3,4-thiadiazole. These conjugated nonaromati c 30 pi -electron macrocycles coordinate three metal ions within their cent ral cavity and constitute one of the rare examples of expanded heteroazapor phyrinoids.