N. Hayashi et al., Toward the creation of NMR databases in chiral solvents for assignments ofrelative and absolute stereochemistry: Scope and limitation, ORG LETT, 3(14), 2001, pp. 2249-2252
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Three additional NMR databases, 1-3, in a chiral solvent are presented. The
C.21-C.38 portion of oasomycin A is used to demonstrate the scope and limi
tation of the universal NMR database approach in a chiral solvent for assig
nment of relative and absolute stereochemistry without degradation and/or d
erivatization.