The study of nonlinear dynamical systems is a subject of much interest, one
application being in secure communication systems realized through the syn
chronization of chaotic dynamical systems. In this paper optical coupling i
s used to effect synchronization between two diode lasers in a master-slave
configuration, and we study the effect of frequency detuning between the m
aster and slave lasers on the character of the observed synchronization. Ex
perimental conditions are found under which the synchronization plot (forme
d by plotting the output power of the slave laser against that of the maste
r at each instant in time) makes a transition from a positive gradient to a
negative gradient. The appearance of such a negative gradient is a new phe
nomenon, to our knowledge, which we term "inverse synchronization." A rate-
equation model is proposed which accounts for light injection into the slav
e laser, and which agrees with the experimental results. Using this model,
we establish that inverse synchronization is caused by nonresonant coupling
between the master and slave lasers.