Ma. Continentino et al., Specific heat and magnetization studies of Fe2OBO3, Mn2OBO3, and MgScOBO3 - art. no. 014406, PHYS REV B, 6401(1), 2001, pp. 4406
In this paper we report magnetic and specific heat results for the oxyborat
es Fe2OBO3 and Mn2OBO3. The former presents L-type ferrimagnetism while the
latter presents weak ferromagnetism in distinct ranges of temperature. The
Curie constant for Mn2OBO3 is normal while that for Fe2OBO3 is unusually h
igh, as a consequence of short-range ferromagnetic order. The specific heat
of both systems at low temperatures is dominated by the magnetic excitatio
ns of the ordered magnetic phases. In order to subtract the lattice contrib
ution to the specific heat in these systems, we measured the specific heat
of the nearly isostructural, nonmagnetic compound MgScOBO3. The remaining s
pecific heat contains a magnetic part and an additional component associate
d with charge delocalization.