Ferromagnetism was recently observed at unexpectedly high temperatures in L
a-doped CaB6. The starting point of all theoretical proposals to explain th
is observation is a semimetallic electronic structure calculated for CaB6 w
ithin the local density approximation. Here we report the results of parame
ter-free quasiparticle calculations of the single-particle excitation spect
rum which show that CaB6 is not a semimetal but a semiconductor with a band
gap of 0.8 +/- 0.1 eV. Magnetism in LaxCa1-xB6 occurs just on the metallic
side of a Mott transition in the La-induced impurity band.