Vv. Kaminskii et al., The mechanism of the appearance of an electromotive force on heating of SmS single crystals, PHYS SOL ST, 43(6), 2001, pp. 1030-1032
We analyze the experimental variation of the concentration of conduction el
ectrons in semiconducting SmS single crystals with increasing temperature w
ithin a shallow-impurity model. it is shown that the appearance of an elect
romotive force is due to accumulation of the critical concentration of free
electrons, which results in screening of the Coulomb potential of Sm2+ imp
urity ions that are responsible for the creation of donor levels with an ac
tivation energy of 0.045 eV in the band gap of SmS single crystals. (C) 200
1 MAIK "Nauka/Interperiodica".