Pyrazol-4-yl-substituted alpha-nitronyl and alpha-imino nitroxide radicalsin solution and solid states

Authors
Catala, L Feher, R Amabilino, DB Wurst, K Veciana, J
Citation
L. Catala et al., Pyrazol-4-yl-substituted alpha-nitronyl and alpha-imino nitroxide radicalsin solution and solid states, POLYHEDRON, 20(11-14), 2001, pp. 1563-1569
Citations number
33
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
POLYHEDRON
ISSN journal
02775387 → ACNP
Volume
20
Issue
11-14
Year of publication
2001
Pages
1563 - 1569
Database
ISI
SICI code
0277-5387(20010530)20:11-14<1563:PAAANR>2.0.ZU;2-L
Abstract
The synthesis, solution studies, X-ray structures and magnetic properties o f two new radical derived pyrazole ligands, based on alpha -nitronyl and im ino nitroxides are reported. The spin distribution on the radicals has been studied in solution using EPR spectroscopy on dilute solutions. In concent rated solutions the radicals form aggregates in solution in which the magne tic interactions have been studied using low-temperature EPR spectroscopy. (C) 2001 Elsevier Science Ltd. All rights reserved.