Mechanochemical synthesis of tri-mu(2)-disulfido-mu(3)-thio-tris(diethyldithiocarbamato)-S,S '-triangular-trimolybdenum diethyldithiocarbamate {Mo-3(mu(3)-S)(mu(2)-S-2)(3)[(C2H5)(2)NCS2](3)}(+)[(C2H5)(2)NCS2](-)

Authors
Volkov, VV Myakishev, KG Il'inchik, EA
Citation
Vv. Volkov et al., Mechanochemical synthesis of tri-mu(2)-disulfido-mu(3)-thio-tris(diethyldithiocarbamato)-S,S '-triangular-trimolybdenum diethyldithiocarbamate {Mo-3(mu(3)-S)(mu(2)-S-2)(3)[(C2H5)(2)NCS2](3)}(+)[(C2H5)(2)NCS2](-), RUSS J C CH, 27(6), 2001, pp. 398-400
Citations number
10
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
RUSSIAN JOURNAL OF COORDINATION CHEMISTRY
ISSN journal
10703284 → ACNP
Volume
27
Issue
6
Year of publication
2001
Pages
398 - 400
Database
ISI
SICI code
1070-3284(200106)27:6<398:MSOT>2.0.ZU;2-H
Abstract
The mechanoactivated solid-state reaction of [Et4N](2)[Mo3S7Br6] With Na(Et 2NCS2) in a vacuum vibration ball mill yields the [Mo3S7(Et2NCS2)(3)](+)[Et 2NCS2](-) complex. The product was studied by IR and Raman spectroscopy and differential thermal analysis.