Influence of packing of radical cations on the conductivity of the new molecular semiconductor (Doet)(2)ReO4

Citation
Vv. Gritsenko et al., Influence of packing of radical cations on the conductivity of the new molecular semiconductor (Doet)(2)ReO4, RUSS J C CH, 27(6), 2001, pp. 401-406
Citations number
11
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
RUSSIAN JOURNAL OF COORDINATION CHEMISTRY
ISSN journal
10703284 → ACNP
Volume
27
Issue
6
Year of publication
2001
Pages
401 - 406
Database
ISI
SICI code
1070-3284(200106)27:6<401:IOPORC>2.0.ZU;2-H
Abstract
A new molecular semiconductor, (Doet)(2)ReO4 (Doet is (1,4-dioxanediyl-2,3- dithio)ethylene-dithiotetrahiafulvalene), is synthesized and examined by X- ray diffraction analysis. The crystal structure of (Doef)(2)ReO4 is Formed by [Doet](+1/2) layers with isle [ReO4](-) anions located between them. The Doet radical cations from the adjacent layers are linked by intermolecular hydrogen interactions of the (OH)-H-... type.